1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 8): o2327, 2012 Aug 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-22904799
RESUMEN
In the title hydrated molecular salt, C(2)H(10)N(2) (2+)·2C(8)H(9)N(2)O(4) (-)·H(2)O, an intra-molecular O-Hâ¯O hydrogen bond occurs in the anion, forming an S(7) ring. The -CO(2) and -CO(2)H groups make dihedral angles of 3.2â (2) and 2.0â (3)°, respectively, with the five-membered ring. In the crystal, N-Hâ¯O, N-Hâ¯N and O-Hâ¯O hydrogen bonds lead to the formation of a three-dimensional supra-molecular architecture. The methyl group in the anion is disordered over two sets of sites in a 0.716â (9):0.284â (9) ratio. The ethylenediamine cation is generated by symmetry and the water molecule lies on a twofold axis.